Enamel remover

ABSTRACT

PCT No. PCT/JP95/02286 Sec. 371 Date May 15, 1997 Sec. 102(e) Date May 15, 1997 PCT Filed Nov. 9, 1995 PCT Pub. No. WO96/14823 PCT Pub. Date May 23, 1996An enamel remover, which contains acetone, ethylene carbonate, and a monohydric lower alcohol at a specific ratio, has a notable effect for removing enamel painted on nails and has no stimulant odor in use. In addition, it does not damage nails or skin.

FIELD OF THE INVENTION

The present invention relates to an enamel remover, more specifically to an enamel remover which has a sufficient removing ability and which has no stimulant odor and gives no damages such as whitening to nails and skins.

DESCRIPTION OF THE RELATED ART

As for an enamel remover used for removing an enamel coated on nails, removers in which acetone, ethyl acetate, and butyl acetate are blended in large quantities have so far been widely used because of strong removing power thereof. However, because of a strong stimulant odor in the use thereof and a strong dehydrating power and degreasing power thereof, nails and skins are often damaged. Proposed in JP-A-7-17832 as a countermeasure therefore are an one containing propylene carbonate and aliphatic alcohol as main components and an enamel remover containing ethylene carbonate and monohydric lower alcohol as main components.

However, users usually paint enamel twice in order to prolong a life of the enamel on nails, and among them, some users paint the enamel three or more times one over another or use the enamel in combination with a base coat and a top coat. In such cases, it has been impossible to remove the enamel rapidly enough with conventional enamel removers.

JP-A-01 242 515 discloses a nail lacquer remover containing 40-60% propylene carbonate, 20-40 weight % ethanol, 0.1-5 weight % of hydroxypropyl cellulose and 0-40 weight % water as essential components. This composition is described as not damaging nails, not having a solvent smell and not raising the danger of ignition.

JP-A-01 160 908 reveals an enamel nail remover comprising 5.0-70.0 weight % acetone, 5.0-50.0 weight % water, 5.0-50.0 weight % propylene carbonate, 0.5-30.0 weight % liquid oil of hydrocarbon and 0.5-30.0 weight % hydrocarbon solvent.

In U.S. Pat. No. 4,801,331, a nail lacquer remover composition is disclosed which essentially consists of 30-65% by weight of a carbonate selected from ethylene carbonate, propylene carbonate, butylene carbonate and glycerine carbonate; 10-50% by weight of 1,3-dimethyl-2-imidizolidinone; 0.2-20% by weight of hydroxypropyl cellulose; and 13-40% by weight of water.

Accordingly, it has been desired to develop an enamel remover which satisfies sufficiently the above users and does not damage nails and skins and which has no stimulant odor in the use thereof.

BRIEF DESCRIPTION OF THE DRAWING

FIG. 1 is a drawing showing a preferred composition ratio of three structural elements of the composition of the present invention. The concentrations of the components shown in the drawing are the concentrations of the respective components, based on the whole amount of (A), (B) and (C).

SUMMARY OF THE INVENTION

Intensive investigations made by the present inventors in view of the above existing circumstances have resulted in finding that an enamel remover, which will be described below, provides remarkable advantages for removing enamel on nails and has no stimulant odor during the use thereof and that the nails and skins are not damaged thereby, and have come to complete the present invention.

The present invention provides an enamel remover characterized in that it contains acetone, ethylene carbonate, and monohydric C₁ -C₆ alcohol and the combination thereof as essential components in a specific range makes it excellent in terms of a removing power, odor and prevention of damage of nails.

DETAILED DESCRIPTION OF THE INVENTION

The present invention provides an enamel remover composition comprising:

(A) ethylene carbonate or propylene carbonate,

(B) acetone, and

(C) monohydric C₁ -C₆ alcohol,

wherein contained are (A) in a proportion of 5 to 40 wt %, (B) acetone, and 25 to 50 wt % and (C) in a proportion of 10 to 60 wt %, based on the whole amount of (A)+(B)+(C).

Preferable contained are 10 to 30 wt % of (A) ethylene carbonate or propylene carbonate, 25 to 40 wt % of (B) acetone, and 30 to 55 wt % of (C) monohydric C₁ -C₆ alcohol. This range of (A) is preferred from the viewpoint of the removing power. This range of (B) is preferred from the viewpoint of a good odor and a good feeling in touch. This range of (C) is preferred from the viewpoint of after-sensation after use.

these two composition ratios are shown by pentagons of chain lines, respectively, in the attached drawing. Particularly preferred is a composition ratio falling in a range surrounded by two curved solid lines in the attached drawing.

It is preferable that the component (A) is ethylene carbonate.

The monohydric C₁ -C₆ alcohol component (C) includes ethanol, n-propanol, i-propanol, n-butanol, n-pentanol, and n-hexanol. Of them, ethanol, n-propanol and i-propanol are preferred, and ethanol is particularly preferred.

The present invention further provides a method for removing nail enamel from nails with the composition described above.

Further, the composition of the present invention contains water. The composition further contains at least one of an ester series oil component, polyols, and carbitols.

Water can be further blended into the enamel remover of the present invention in order to endow nails with a moisture retention property. Blending it in a proportion of 0.1 to 16%, preferably 0.5 to 5% can make nails moist.

An ester series oil component can be further blended into the enamel remover of the present invention in order to make up for an oil content of nails. T o be concrete, there can be given glycerine esters such as triglyceride 2-ethylhexanoate, isostearylmyristoyl glyceride, and triacetin, diesters such as diisopropyl adipate, diisobutyl adipate, and dipropyl succinate, and aromatic esters such as diethyl phthalate and dibutyl phthalate.

Polyols and carbitols can be further blended into the enamel remover of the present invention in order to endow nails with a moisture retention property. To be concrete, there can be given glycerine, propylene glycol, 1,3-butylene glycol, and isoprene glycol as polyols, and ethyl carbitol and diethyl carbitol as carbitols.

The ester series oil component, polyols and carbitols each described above are blended into the enamel remover of the present invention so that the blending amount of one or two more of them is preferably 0.1 to 10%, particularly preferably 2 to 8%.

Components usually used for an enamel remover, for example, hydrocarbon series oil components such as liquid paraffin, silicon series oil components such as methyl polysiloxane, surfactants, various chemicals, perfumes, and dyes can be blended into the enamel remover of the present invention according to necessity as long as the effects of the present invention are not damaged.

The surfactants can be blended in order to improve a stability of the enamel remover of the present invention. Nonionic surfactants are preferred since they do not stimulate nails and skins, and the concrete examples thereof include linear secondary higher alcohols such as polyoxyethylene (hereinafter shown by "POE")-sec-tetradecyl ether, POE-glycerine fatty acid esters such as POE-glycerine monostearate and POE-glycerine tristearate, and POE-alkylphenyl ethers such as POE-octylphenyl ether and POE-nonylphenyl ether.

The enamel remover of the present invention is prepared by mixing the essential components described above by conventional method s and stirring evenly them.

The enamel remover of the present invention has a notable effect for removing enamel painted on nails and has no stimulant odor in the use thereof while containing acetone. It can display the performances described above without damaging nails and skins. The enamel remover of the present invention can favorably be used for removing every enamel such as nitrocellulose series enamel and aqueous enamel using an acrylic resin.

EXAMPLES

The present invention will concretely be explained below with reference to examples but the present invention will not be restricted thereto. Examples 1 to 4 and Comparative Examples 1 to 7

The enamel removers having the compositions shown in Table 1 were prepared by mixing evenly the respective components.

                  TABLE 1                                                          ______________________________________                                         (%)                                                                                     Example   Comparative Example                                         Composition                                                                               1     2     3   4   1   2   3   4   5   6   7                       ______________________________________                                         Acetone    23    36    40  33  --  40  65  --  30  68  68                      Ethylene carbonate                                                                        14    13    23  20  --  --  --  30  65  25  17                      Propylene carbonate                                                                       --    --    --  --  75  --  --  --  --  --  --                      Ethanol    53    41    26  41  25  53  30  63  --  --  10                      Glycerine   3    --     3  --  --  --  --   3  --   2  --                      2-Ethylhexanoic                                                                           --     5    --   5  --   3   4   3  --  --  --                      acid triglyceride                                                              1,3-Isostearyl-                                                                            3    --     3  --  --   3  --  --   3   3   3                      myristoyl                                                                      diglyceride                                                                    Water       4     5     5   1  --   1   1   1   2   2   2                      ______________________________________                                    

An aqueous enamel (aqueous polymer emulsion: 90%) was painted once or twice on nails, and a top coat was further painted thereon. After 24 hours, the enamel was removed with the enamel removers obtained above to evaluate the odor and the removing power thereof according to the following criteria:

Evaluation Methods

(1) Odor in the use

AA: Almost no odor

BB: Slight odor

CC: Stimulant odor

DD: Strong stimulant odor

(2) Removing power (when nails are wiped off twice)

AA: Almost all enamel can be removed

BB: Slightly remains

CC: Fairly remains

DD: Scarcely removed

                                      TABLE 2                                      __________________________________________________________________________                 Example     Comparative Example                                                1  2  3  4  1  2  3  4  5  6  7                                    __________________________________________________________________________     Odor in use AA AA BB AA AA CC DD AA AA DD DD                                   Removing power                                                                             AA AA AA AA AA AA AA AA DD AA AA                                   (painted once)                                                                 Removing power                                                                             BB AA AA AA CC AA AA CC DD AA AA                                   (painted twice + top coat)                                                     __________________________________________________________________________

Example 5

An enamel remover having the composition shown below was prepared by mixing evenly the respective components.

                  TABLE 3                                                          ______________________________________                                         Blend composition   (%)                                                        ______________________________________                                         Acetone             36                                                         Ethylene carbonate  10                                                         Propylene carbonate  5                                                         Ethanol             40                                                         Glycerine            2                                                         Glyceryl tri-2-ethylhexanoate                                                                       2                                                         Water                5                                                         ______________________________________                                    

Enamel was removed with the enamel remover obtained above to find that no stimulant odor was found in the use thereof and a good feeling was obtained. In addition, the above enamel remover did not cause whitening and damage on nails.

Example 6

An enamel remover having the composition shown below was prepared by mixing evenly the respective components.

                  TABLE 4                                                          ______________________________________                                         Blend composition   (%)                                                        ______________________________________                                         Acetone             31                                                         Ethylene carbonate  15                                                         Propylene carbonate  5                                                         Ethanol             40                                                         Glycerine            2                                                         Glyceryl tri-2-ethylhexanoate                                                                       2                                                         Water                5                                                         ______________________________________                                    

Enamel was removed with the enamel remover obtained above to find that no stimulant odor was found in the use thereof and a good feeling was obtained. In addition, the above enamel remover did not cause whitening and damage on nails. 

We claim:
 1. An enamel remover composition, comprising:(A) ethylene carbonate, (B) acetone, and (C) one or more monohydric C₁ -C₆ alcohols,wherein contained are (A) in a proportion of from 5 to 40 wt %, (B) in a proportion of 25 to 50 wt %, and (C) in a proportion of 10 to 60 wt %, based on the total amount of (A)+(B)+(C).
 2. The composition of claim 1, which comprises 10 to 30 wt % of (A), 25 to 40 wt % of (B) and 30 to 55 wt % of (C).
 3. The composition of claim 2, wherein (C) is contained in an amount of 30 to 50 wt %.
 4. The composition of claim 1, further comprising water.
 5. The composition of claim 1, further comprising at least one of an ester oil component, polyol or carbitol.
 6. The composition of claim 1, wherein said monohydric C₁ -C₆ alcohol is selected from the group consisting of ethanol, n-propanol, i-propanol, n-butanol, n-pentanol and n-hexanol.
 7. The composition of claim 6, wherein said monohydric C₁ -C₆ alcohol is selected from the group consisting of ethanol, n-propanol and i-propanol.
 8. The composition of claim 7, wherein said monohydric C₁ -C₆ alcohol is ethanol.
 9. The composition of claim 5, wherein said ester oil component is selected from the group consisting of triglyceride 2-ethylhexanoate, isostearylmyristoyl glyceride, triacetin, diisopropyl adipate, diisobutyl adipate and dipropyl succinate.
 10. The composition of claim 5, wherein said polyol is selected from the group consisting of glycerine, propylene glycol 1,3-butylene glycol and isoprene glycol.
 11. The composition of claim 7, wherein said carbitol is selected from the group consisting of ethyl carbitol and diethyl carbitol.
 12. A method for removing enamel from nails, comprising applying the composition of claim 1, to nails. 